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不同光照下的近红外光谱模型传递研究

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作者:张文君, 唐红, 蒋巧勇

作者单位:中国计量学院, 测试计量学院, 浙江 杭州 310018


关键词:近红外光谱;直接校正;光照影响;模型传递;糖度


摘要:

针对室外光照对近红外光谱检测带来误差的问题,提出基于模型传递来减少检测误差的方法。以圆黄梨为样品,分析样品在室内、室外阴影下的近红外光谱,建立室内光谱的偏最小二乘(PLS)模型。采用直接校正(direct standardization,DS)算法,减小室内外光谱差距,使得室内PLS模型能预测室外光谱。结果表明:在室内建立的模型能预测经DS算法传递后的室外光谱,预测决定系数(rp2)和预测均方根误差(root mean square error of prediction,RMSEP)分别为0.71和0.374,能有效解决室外光照对光谱检测的影响。


Research on model transfer of near infrared spectroscopy at different illumination

ZHANG Wenjun, TANG Hong, JIANG Qiaoyong

College of Metrological Technology and Engineering, China Jiliang University, Hangzhou 310018, China

Abstract: To minimize the error in sample detection by near infrared spectrometers outdoor, a method using model transfer to lower the measurement error has been proposed in this paper. The near infrared spectroscopy (NIRS) was used to detect the sample-Wonhuwang pear under outdoor and indoor shadows and the results were analyzed to establish a Partial Least Squares (PLS) model for indoor spectrum. The detection errors between the near infrared spectrums under indoor and outdoor shadows were reduced through Direct Standardization (DS) algorithm to enable the model to predict the near infrared spectrum outdoor. Experimental results show the determination coefficient and root mean square error of prediction are 0.71 and 0.374 respectively. It can lower the effect of outdoor light on spectrum detection.

Keywords: NIRS;DS;illumination;model transfer;sugar

2015, 41(12): 70-73  收稿日期: 2015-06-10;收到修改稿日期: 2015-08-14

基金项目: 浙江省自然科学基金(Y14F020161)

作者简介: 张文君(1990-),女,江苏南通市人,硕士研究生,专业方向为近红外检测技术。

参考文献

[1] Saranwong S, Sornsrivichai J, Kawano S. On-tree evaluation of harvesting quality of mango fruit using a hand-held NIR instrument[J]. Journal of Near Infrared Spectroscopy,2003,11(4):283-293.
[2] 吴方龙,沈黄通,吴晨凯,等. 基于近红外漫反射光谱无损检测梨可溶性固形物的光强影响探究[J]. 光谱学与光谱分析,2013,33(10):2671-2674.
[3] 胡润文,夏俊芳. 脐橙总糖近红外光谱模型传递研究[J].食品科学,2012,33(3):28-32.
[4] 周林峰,吕进,刘辉军. 温度对果糖含量近红外光谱检测模型传递的影响[J]. 中国计量学报,2012,23(3):217-212.
[5] 李庆波,张广军,徐可欣,等. DS算法在近红外光谱多元校正模型传递中的应用[J]. 光谱学与光谱分析,2007,27(5):873-876.
[6] 王菊香,李华,邢志娜,等. 小波多尺度分段直接校正法用于近红外光谱模型传递的研究[J].分析化学,2011,39(6):846-850.
[7] 张建光,刘玉芳,孙建设. 光照强度对苹果果实表面温度变化的影响[J]. 生态学报,2004,24(6):1306-1310.
[8] 王加华,潘璐,李鹏飞,等. 苹果糖度近红外光谱分析模型的温度补偿[J]. 光谱学与光谱分析,2009,29(6):1517-1520.